Here's a neat appearance of the Catalan numbers that I came across by fiddling about with some code. Count the number of lattice walks of length 2n from (0,0) to (0,0) but weight each walk by (-1)^w where w is the winding number around (1/2, 1/2). The result is 4^n C_n, where C_n is the nth Catalan number.
You can think of this as (1) a subcomputation when trying to count lattice walks on a lattice drawn on the Riemann surface for the square root function or (2) the probability amplitude for an electron in a (very simplified model of a) 2D lattice returning to its start point after 2n steps when there's a certain amount of magnetic flux through the "plaquette" next to where it starts. Eg. see https://en.wikipedia.org/wiki/Peierls_substitution